I don't have the answer but I'm going to have the same problem as you, since I stupidly wire wheeled off the cadmium coat on those pins and now they're all rusted to hell. I do know from experience that hammering on any pin won't help get it out because the end you hammer on will compress and expand, and soon It'll have a greater diameter than the hole it's supposed to go thru. A gentle tap should suffice, and if it doesn't, add WD -40 till it does but don't increase the tapping force to the point of being destructive.
I'll probably have to put a little cutting wheel on the Dremel, cut off the tip and drill the rest out, then get new pins from Brembo. Fortunately the pads were new when I took off the rust-protective cadmium, so sounds like you've got a more critical situation...still, new pins might be in your future sooner than mine unless someone else has a better suggestion.