Looking at that valve chart, all i can say is wowza.....If I read it correctly you have 10 of 16 that are too tight, granted not by much, but still outside of the tolerance range, 4 that are at the bare minimum and 2 that are fine.
#3 intake and #4 exhaust both a&b are right at the bare minimum.
#3 exhaust, both are just right.
All the rest are out of spec on the tight side.
BMW says not to(they want to sell you new ones), some riders here will also say not to, yet some riders have, and I have, "re-used buckets" or "moved buckets around" as needed to meet specs, with no ill effects.....
In my case I was able to move a bucket from a valve that was too loose and use it on a valve that had been too tight. It all depends on the thickness of your buckets and where they are at if you can re-use them or not.
The only way you are going to know what you need for new buckets is to pull the cams and inventory exactly what buckets you have and do the math. It may be possible to read the bucket spec, or you may have to measure it with a micrometer.
Re the radiator/engine cooling system, like others have mentioned, do a chemical flush to get as much of that scale out as possible as it does/will inhibit heat transfer, both in the block as well as in the radiator.
We have similar issue where I work, with our industrial chiller air conditioning system. Steel pipes and tap water cause a rusty scale inside the copper tubes of the chiller bundle. Even with continuous chemical treatment we still have to brush out the tubes every year to minimize/reduce/remove the coating inside the tubes that inhibits the heat transfer.